Synthesis, characterization, and  antibacterial activity of some new metal complexes containing semicarbazide

Authors

  • Eman Ahmed College of Education for Pure Science Author
  • Dr. Nasry Jassim Hussien university of Diyala Author
  • Dr.Siti Fairus M.Yusoff Universiti Kebangsaan Malaysia Author

DOI:

https://doi.org/10.69923/IJAS.2024.010104

Keywords:

Antibacterial, activity, metal complexes , Synthesis, Semicarbazide,

Abstract

The research encompassed both the initial setup and detailed description of the N-cyclohexyl-2-((dimethylcabamoyl)carbamothioyl) hydrazine-1-carboxamide (L). Metal ions Co+2  , Ni+2, and Cu+2 were combined with the ligand(L) to form three transition metal complexes .The chemical formulas are the following [LCoCl2H2O] ,[LNiCl2H2O] ,[LCuCl2H2O], was derived from a process in which the metals were mixed in a [1:1]mole ratio with methanol(MeOH) acting as a cofactor. Several physicochemical techniques proved that the ligand and its metal complexes were in the expected structural form ,revealing the structure of the ligand -metal complex.  by the use of numerous infrared spectroscopy (FT-IR) , electronic spectra , nuclear magnetic resonance spectra (1H-NMR and 13C-NMR), molar conductivities, magnetic susceptibility and melting points, Isolation of three-coordinate complexes with deformed octahedral geometry around the core atom was determined by the spectral and analytical investigations for the Co+2 ,Ni+2 and Cu+2 atoms. We looked into its antibacterial properties ,both (G+) and (G-) bacterial

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Author Biographies

  • Eman Ahmed, College of Education for Pure Science

    Eman Ahmed Kadhim is a Master's student at the College of Education for Pure Sciences at the University of Diyala. She obtained a bachelor’s degree in chemistry from the College of Education for Pure Sciences at the University of Diyala. 2016 and she is a teacher at Al-Iraqiya Girls Secondary School . 

  • Dr. Nasry Jassim Hussien, university of Diyala

    Dr. Nasry Jassim Hussien is an associate professor at the College of Education for Pure Sciences at the University of Diyala. He obtained a bachelor’s degree in chemistry from Al-Mustansiriya University and a master’s degree from the University of Technology, Department of Applied Sciences. He obtained a doctorate from the Malaysian University UKM, College of Science and Technology, FST, in the specialty of inorganic chemistry. His areas of research are:  Chemistry includes organic and inorganic aspects and includes the diagnosis of complexes and their applications. He has published several scientific papers in national, and international conferences and journals. He can be contacted at email: nasry.hussien@uodiyala.edu.iq

  • Dr.Siti Fairus M.Yusoff , Universiti Kebangsaan Malaysia

     Dr.Siti Fairus M.Yusoff received a Bachelor of Science (Pure Chemistry) from Universiti Teknologi Malaysia (2007) and a Doctor of Philosophy in the same field from the University of Bristol in the United Kingdom (2011). Currently, she is a senior lecturer at the Faculty of Science and Technology, Universiti Kebangsaan Malaysia. Her research focuses on the development of polymer and inorganic materials for different applications, such as wastewater treatment, agriculture, and biomedicine has published several scientific papers in national, and international conferences and journals. She can be contacted at email: sitifairus@ukm.edu.my

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Published

06/30/2024

Issue

Vol. 1 No. 1 (2024)

Section

Articles

License

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References

Marshall,G.C.and H.W.Ohm 1987 .Yield responses of 16 winter wheat cultivars to row spacing and seeding rate .Agronomy Journal .79:1027-1030

How to Cite

[1]
“Synthesis, characterization, and  antibacterial activity of some new metal complexes containing semicarbazide”, IJApSc, vol. 1, no. 1, pp. 36–49, Jun. 2024, doi: 10.69923/IJAS.2024.010104.

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